Mission: The Environmental Defense Fund is perhaps the most wide-ranging organization on this list, working to provide solutions under the broad categories of climate change, oceans, wildlife and habitats, and health. We chose environment-focused organizations where your donation goes furthest, including its Charity Navigator score, which breaks down how organizations use donations and how transparent they are about it.Įnvironmental Groups That Actually Affect Change 1. There are many worthy organizations doing great work for the outdoors that are worth supporting, but as we say good riddance to 2016 and hope for a better 2017, here’s a good place to start. “People are realizing-particularly after some of the cabinet picks is making, like for the Environmental Protection Agency-that some of the work they have been taking for granted might be under threat.” The same is true at the Trust for Public Land, which saw a 35 percent increase in online donations the week after the election, according to spokesman Tim Ahern. More than 50,000 donors have interacted with the organization in the past month, which is much higher than average for this time of year. Mogerman has seen an exponential increase in online action, responses to emails, and financial support since the election. “We’re not planning to stop pushing for stronger environmental protections in D.C., but it’s likely that those fights are going to be even harder and more forceful,” says Josh Mogerman, a spokesman for the Natural Resources Defense Council. If you didn’t vote for Donald Trump, the change you’d like to see likely isn’t going to come from the top down, so it’ll have to come from the organizations who have been fighting the good fight from the bottom up for decades. This one, however, won’t cater so enthusiastically to cyclists, or anyone else who cares about the outdoors, the environment, and conservation. While the event, aptly named the Tour de Trump, only lasted a few years, it’s safe to say that following the recent presidential election we are all on a kind of Tour de Trump-and it’s going to last at least four years. In 1989, Donald Trump put on an 837-mile bike race from Albany to Atlantic City that aimed to rival the Tour de France.
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Such was the case with the Blonde vinyl, and it continues to be the case now that bootlegged versions of the Blonde vinyl are on the rise.Ĭurrently, the cost of an original Blonde vinyl is at an all-time high, especially if the Blonde vinyl is still sealed. Read More: Why Do Musicians Smash Their Instruments? (9 Reasons Why) Naturally, limited editions with numerous interested buyers end up with higher prices, as there is a guarantee that people are willing to spend a lot of money to acquire the goods. In fact, it is believed that only 1,000 copies of the Blonde vinyl were ever made. Mainly, this is because the Blonde vinyl is a limited edition format of the album. While increased demand for the Blonde vinyl was good news for Frank Ocean and his associates, it was not for the many fans that wanted a copy. Naturally, Blonde’s release in vinyl form was welcomed with open arms by Frank Ocean fans, as vinyl is a new way of experiencing Frank Ocean’s music.Īs demands for the Blonde vinyl increased, so did the vinyl’s price. That said, when Blonde finally came out in August 2016 in digital and CD format, it ranked first in the music charts of over five countries and within the top ten hits in others. There Is A High Demand For The Blonde Vinylīlonde was only Frank Ocean’s second studio album, but the anticipation for Blonde’s release was already intense. Why is the Blonde vinyl so expensive? Here is what I found! Why Is Blonde Vinyl So Expensive?ġ. If you are hearing about Blonde vinyl only now, however, you might be a little hesitant to make the purchase. Lonny Breaux)J5 So Fresh J6 Standing Still K1 Stay If You Go K2 Sucka For Love K3 Sucker For LoveK4 Surprise Ending (ft.Blonde is one of the hottest albums to come out in the past decade, and when a vinyl version was released, Frank Ocean fans were quick to get a copy. Lonny Breaux)E3 Kamikaze E4 Know Better E5 Lights F1 Lonny (New Mix) F2 Lost Angel (No 2nd Verse) F3 Lost Angel F4 Love On My Piano F5 Miss You So G1 No Bonnie G2 No Love G3 Non-Stop G4 Ohh In Love G5 Old Terror H1 One Look H2 Open Air H3 Overload H4 Private Show H5 Quickly I1 Read The Stars I2 Ready I3 Real I4 Rewind That I5 Richest Man In The Room I6 Rocket Love J1 Scared Of Beautiful J2 She Won't Say Hello J3 Simply J4 So Comfortable (ft. Lonny Breaux)C1 Flight C2 Focus C3 Follow C4 Go Up C5 Got The Keys D1 Greedy Love D2 Hardest Thing D3 Holly Baby D4 I Need Love D5 If I'm In Love E1 J.O.B E2 James Fauntleroy - Dying For Your Love (ft. Tracklist - A1 Acura Integurl A2 Bedtime Story A3 Blasted (Prod Midi Mafia)A4 Bricks And SteelA5 Broken Pieces B1 Can't Be The Last Time B2 Day Away B3 Denim B4 Done B5 Dying For Your Love (ft. Over the years, numerous reference tracks have leaked out onto the Internet to be collected by fans. Before signing a deal with Def Jam or linking up with Odd Future, Frank was writing songs under the name Lonny Breaux. Shipping to some countries may take longer.įrank Ocean may seem like a house hold name to most, but he's been recording tracks for a lot longer than it took to make it. International buyers - price does not include any import or other such taxes that may apply in your country, and you also accept liability for any delays or obstacles to receipt of the package resulting from the administration of the import process by your country’s authorities. Willing to post international, however shipping costs will increase. Dispatch time 2 days however this may take longer due to lockdown restrictions still in place in Northern Ireland. Condition is New.ĭispatched with Royal Mail signed for. Frank Ocean - The Lonny Breaux Collection Vinyl 6LP Brand New. You can now take the stage - anywhere, anytime - using your ultra portable iOS device as the brains of the DJ booth. Welcome to the new era of DJing - control djay on your iPhone, iPad, Mac or Windows with professional turntables and mixers. Cue point colors for tracks are seamlessly synchronized across djay on Mac, iPad, and iPhone via the cloud. Introducing the world’s first AI DVS system.
Learning to craft metal is possible with a few clicks at Alibaba. There is also a variety of metal craft paint available, depending on the finished look you have envisioned. Examples of metals are canelt used and cast into different shapes through hollow and solid casting. Many of the Emperors gave specific commands or instructions that only royalty or those with prestige and power could possess Pixiu statues. They make your house attractive and classy. Because of the reputation for being ferocious, fearless, and powerful, the image of the Pixiu became closely tied to the ancient Chinese army, and was used on flags and other identification markers. However, nowadays, you can find aixiu statue in many homes. Rulers and nobles majorly used these crafts to signify royalty and class in the past. FUQILALA Pair of Pixiu Statue Feng Shui Decor-Green pi xiu/pi yao Statue-Wealth Prosperity Home Decoration Figurine. 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Apple also shoed off pricy mixed-reality headgear called the Vision Pro at its annual Worldwide Developers Conference, challenging Facebook-owner Meta in the mixed-reality market. Developers can browse content by topic, register for Digital Lounges and one-on-one lab consultations, watch videos with their peers using SharePlay, copy code directly from session videos, read feature stories, and more.ĭevelopers can also access all WWDC content, registration, news, feature stories, and documentation at . Apple WWDC 2023 Highlights: Apple introduces a new MacBook Air alongside new operating systems for iPhone, iPad, Mac and Apple Watch. The Apple Developer app is a great way to experience WWDC22 on Mac, iPhone, iPad, and Apple TV, with daily updates and notifications on the latest news, content, and activities. Building on the success of the past two years of virtual events, WWDC22 will showcase the latest innovations in iOS. Cupertino, California Apple today announced it will host its annual Worldwide Developers Conference (WWDC) in an online format from June 6 through 10, free for all developers to attend. The Worldwide Developers Conference (WWDC) is one of the biggest events of the year for Apple developers, and this year. Apple to again host Swift Student Challenge. The event gives students of all ages the opportunity to showcase their love of coding by creating their own Swift Playgrounds app project. Everything Apple announced at WWDC 2021: iOS 15, MacOS Monterey, and more. With the announcement of the Swift Student Challenge winners today, Apple continues to celebrate student developers from all over the world. Try a coding or design challenge, participate in a Q&A, meet session presenters, and more. In addition to sessions and lab consultations, Apple engineers and designers will host activities all week in Digital Lounges to help developers engage in technical discussions, get answers to their questions, and connect with the community. Apple Developer Program members, Apple Developer Enterprise Program members, and 2022 Swift Student Challenge award recipients can request one-on-one lab appointments with Apple experts for guidance on implementing the latest technologies, following best practices, and designing their apps.īeginning June 7, session videos will be posted daily on the Apple Developer app and the Apple Developer website. However, the biggest announcement of the event flew under the radar, and. Featuring over 150 in-depth session videos, WWDC22 brings together the latest tools and technologies to give developers the chance to learn how they can create the next generation of apps. Apple announced a ton of new Macs at WWDC 2023, including the 15-inch MacBook Air and a long-awaited update to the Mac Pro. This tendency to absorb humidity from the environment is due to the basicity of Ca ions 2+.īasicity of what kind: Lewis or Bronsted? From Lewis, due to the fact that the positive species is capable of accepting electrons. It is a white, odorless and hygroscopic solid. Properties Physical properties and deliquescence The product of interest from this process is actually sodium carbonate, Na 2CO 3. However, its main source comes from the Solvay process, in which limestone (CaCO 3) undergoes a series of transformations until resulting in the by-product calcium chloride:ĢNaCl (aq) + CaCO 3(s) Na 2CO 3(s) + CaCl 2(ac) The natural sources of this compound are the brines extracted from the seas or lakes. In medical practice it is also useful in the treatment of depression caused by an overdose of magnesium sulfate, as well as in lead poisoning. It is used as a preservative in some foods, as well as an additive in several of these, such as energy drinks used by athletes, cheeses, beers, etc. Because it is a hygroscopic salt, calcium chloride can be used as a desiccant, being able to lower the humidity of the air that surrounds it and, therefore, of the substances in contact with that air. The sedimented calcium fulfills this function. It is added to pools to reduce the erosion suffered by the concrete of their walls. CaCl liquids 2 increase the efficiency of drilling for the extraction of gas from its underground deposits, as well as that of oil. Accelerates the drying speed of concrete once poured. For this reason it is used to reduce the risk of the movement of people and vehicles during the cold season. Calcium chloride generates a lot of heat as it dissolves and then, as the temperature increases, the ice melts. Avoid freezing the water during winter. However, these structures are less stable than those erected by electrostatic interactions (Ca 2+ and Cl –) of the anhydrous salt. This means that the CaCl 26H 2Or it can adopt other complex structures, to the point of being considered crystalline polymers of calcium and water. At this point the octahedron is "watery" and the molecules are now able to interact with each other by hydrogen bonds (Ca 2+ OH-H-OH 2).Ĭonsecutively, calcium can accept even more water molecules without altering the set ratio. When all Cl ions – are replaced by water molecules, the hydrate CaCl is formed 26H 2O. This fact modifies the crystalline structure and, as the water replaces the green spheres, the more the arrangement of the ions changes. Four of these lie in a square plane and the other two are located perpendicularly (the green spheres farthest from the white sphere).Īs a result of the arrangement of these ions, around Ca 2+ an octahedron is "assembled", thus assigning it an octahedral molecular geometry.Ĭonsidering how the green spheres are arranged, a water molecule can replace one of these, which happens with CaCl 2H 2Or possibly in the square plane. In the center of the parallelepiped the Ca 2+ It is surrounded by six Cl –. Molecular geometry and aqueous calcium complexes In the case of Cl –, it has an additional electron that cannot be attracted with the same force, consequently increasing its ionic radius. This is because, when they lose electrons, the nuclei of the atoms exert a greater attractive force on the outer electronic shells, which reduces the ionic radius. On the other hand, Ca ions 2+ have smaller ionic radii than Cl ions –. In conditions of low humidity, it is possible to keep anhydrous salt free of water, although its natural tendency is to absorb it until it dissolves (deliquescence). Solid portions of CaCl are illustrated in the upper image 2. When x = 0, the salt lacks water and is anhydrous, as indicated by its chemical formula mentioned above. Likewise, it is always accompanied by water molecules, forming hydrates of general formulas CaCl 2XH 2Or, with x = 0, 1, 2, 4 and 6. In this compound there are several electrostatic interactions that define the external appearance of its crystals and the rest of its physical properties. The calcium chloride (CaCl 2) It is an inorganic salt composed of calcium, alkaline earth metal and chlorine halogen. Molecular geometry and aqueous calcium complexes.Video: How to Draw the Lewis Structure of CaCl2 (calcium chloride, ionic) Content Apple stated that: “This Rapid Security Response provides important security fixes and is recommended for all users.” The update requires the iPhone to shut down and restart and is about 85.2MB. This was the first time Apple had used the Rapid Security Response system on a regular public release, the ability to release these RSRs means Apple can patch security vulnerabilities quickly, rather than waiting for a larger version release that can take weeks to test. iOS 16.5 also included 40 security updates across all aspects of the system, from the Weather app to the cellular modem. Additionally, the update fixes three WebKit flaws that have been actively exploited, two of which were fixed in the iOS 16.4.1(a) Rapid Security Response update earlier in May.Īpple issued a Rapid Security Response update for iOS 16.4.1 on 2 May. It also fixes an issue that prevents charging with the Lightning to USB 3 Camera Adapter.”Īpple released iOS 16.5 on May 18, iOS 16.5 includes a new multi-view sports view and Sports tab in Apple News, Pride wallpaper, a Podcast fix for CarPlay and a fix for a Screen Time issue. Apple described as iOS 16.5.1 “important security fixes and is recommended for all users. This security measure verifies the authenticity of iMessage users and is aimed at those with high-security demands (like those targeted by state-sponsored digital threats).Īpple updated iOS 16 on June 21 with security fixes. iOS 16.6 beta also contained code to enable iMessage Contact Key Verification. Apple admitted that it was aware that two of the security issues may have already been actively exploited in the wild (although one of these was addressed in 16.5.1). IOS 16.6 arrived on July 24 and is a maintenance release that contains important bug fixes and several security updates, including fixes for multiple Kernal and Webkit issues. Dry the piece thoroughly (moisture can contribute to tarnish) then polish and buff with a jewelry polishing cloth.Monitor as it is soaking to be sure the oxidization is not stripped from the details of the jewelry. The baking soda will react with the aluminum to lift tarnish. Soak metals for approximately 2-5 minutes.Shake in some baking soda, approximately ¼ teaspoon.Line a small dish with aluminum foil and fill it with very hot water.In the case of heavy build-up, create a natural dip to lift tarnish: Regular maintenance of your jewelry will help keep pieces from building excessive tarnish. Brass or bronze jewelry will tarnish more quickly than sterling silver, but can easily have its shine restored. Though it contains anti-tarnishing agents, all fine sterling silver does eventually tarnish with age and exposure to various elements. How do you keep jewelry from tarnishing, particularly brass jewelry? For sterling silver pieces, you can use a standard silver cleaner, if a polishing cloth is not enough. How do I clean my Waxing Poetic jewelry, particularly bronze pieces?įor cleaning, it is safe to use a polishing cloth lightly water is not recommended. We do regularly get questions about these from our customers on the best practices for maintaining their jewelry, and will answer some of the most common questions here in hopes that it will help you enjoy your jewelry for even longer. At Waxing Poetic, we always use the finest alloys on the market for our sterling silver, brass, and bronze pieces. This makes it easier to see if the battery has deteriorated over time or not.ĭownload coconutBattery app for macOS for free here. Other information that you can see for your iPhone or MacBook include current temperature, current charge in mAh, full charge capacity and design capacity.Ī great feature of this app makes it possible for you to save the current health information of the device, so you can compare it with the future status. The utility reports information about age of the mobile device and its battery, battery health, cycle counts, temperature, and any other saved history. You can also see the battery’s charge cycles that tell you how many times it has been recharged over its lifetime. coconutBattery is a 3rd-party utility for Mac OS X (now macOS) developed by coconut-flavoursic to monitor the battery health of Apple devices with an internal battery, including iPhones. Using coconutBattery app you can see the age of your device, its manufacturing date and the status of its battery. With this free application you can see the current battery health of your iOS device as well as your MacBook. CoconutBattery also says that after 25 charging cycles the. This difference cannot be explained with round ups to zero decimal places. CoconutBattery Your Mac Battery s Health Simplified Oscars Selfies Free. CoconutBattery app shows different battery state of charge then the built in app There is a significant difference between the battery SoC shown by the coconutBattery gauge and the MacOS built in battery app. Now, assuming battery wear of 20 percent over the 500 charge cycles, lets reduce the single charge cycle by 10 percent to get an average over the. There are many tools out there that let you check this information, however if you have a Mac, then you should check out coconutBattery app. Pocket Light Meter Is A Must Have App For Film Photographers iPhone Nintendo. Replacing the iPhone battery can make it performance faster as it brings the CPU performance back to normal. Here is th direct URL Iink ( COCONUT BATTERY D0WNLOAD ). With Apple admitting that it slows down iPhone’s performance to give user a longer battery life, many want to check the health of their device to see if they need a battery replacement on their iPhone, iPad or iPod touch. Our crowd-sourced lists contains more than 25 apps similar to CoconutBattery 3 for Mac, Windows, Android, iPhone and more. 100 Safe and Secure Displays info about your Mac and iOS device battery. In 2008, Wilson produced the film Mamma Mia!, and eight years later its sequel, Mamma Mia! Here We Go Again. The other four depicted on stamps were the filmmaker Costa-Gavras, engineer and entrepreneur Peter Diamandis, journalist George Stephanopoulos, and billionaire businessman John Catsimatidis. Wilson's own Greek heritage was honored in 2016 when the Greek Postal Service ELTA commemorated her with a stamp along with five others. A sequel, My Big Fat Greek Wedding 2, which Wilson co-produced and in which she had a supporting role, was released in 2016. Wilson produced two stage productions of the play, as they were developing the film. She was instrumental in helping actress-playwright Nia Vardalos get the movie deal for My Big Fat Greek Wedding, which became the highest-grossing independent film of all time and for which she served as a producer. She guest starred in many series, including Frasier, Curb Your Enthusiasm, Law & Order: Special Victims Unit, Body of Proof, and had recurring roles on The Good Wife and Girls. On television, she played Susan Borman, wife of astronaut Frank Borman, in the HBO miniseries From the Earth to the Moon. She has appeared in numerous films, including Volunteers, Barbarians at the Gate, The Bonfire of the Vanities, Mixed Nuts, Sleepless in Seattle, Now and Then, That Thing You Do!, Jingle All the Way, Runaway Bride, Invisible Child, The Story of Us, Raise Your Voice, It's Complicated, and Larry Crowne. In the 1980s, Wilson attended the London Academy of Music and Dramatic Art in England. She also twice appeared on M*A*S*H in 1982 as Nurse Lacey as well as the sitcoms Three's Company and Bosom Buddies starring her future husband Tom Hanks, and as Hester Rose Crane, the deceased mother of Frasier Crane on Frasier. Wilson's career began with a guest appearance on The Brady Bunch in the 1972 episode "Greg's Triangle," where she played Pat Conway, one of the candidates running against Marcia Brady for head cheerleader. Career Film, television, theater Wilson at the HBO Post- 60th Primetime Emmy Awards Party in 2008 In addition to Bulgarian, her father could speak "Russian, Turkish, Polish, Greek, a little bit of Italian, a little bit of French" according to Wilson's husband Tom Hanks, who said he modeled his portrayal of the character Viktor Navorski in the film The Terminal on his father-in-law. Wilson was raised in the Greek Orthodox faith. The family lived in Los Angeles, where Wilson's father worked as a bartender. He converted from Islam to Orthodox Christianity upon his marriage and changed his name to Allan Wilson in 1960, choosing his name after a local street. He moved from Bulgaria to the US in 1949. Her father's family moved to Bulgaria when he was a child. Her father, Hassan Halilov Ibrahimoff ( Bulgarian: Хасан Халилов Ибрахимов 1920–2009), was a Bulgarian Muslim ( Pomak) born in Oraio (Breshtene), Greece, close to the border with Bulgaria. Her mother, Dorothea Tzigkou ( Greek: Δωροθέα Τζίγκου), was Greek, raised in Sotirë near Dropull i Sipërm in Albania, close to the border with Greece. Rita Wilson was born Margarita Ibrahimoff in Los Angeles where she grew up. In March 2019, she received a star on the Hollywood Walk of Fame. As a singer-songwriter, Wilson has released the albums AM/FM, Rita Wilson, Bigger Picture, and Halfway to Home. Wilson has performed on Broadway and produced several films, including My Big Fat Greek Wedding (2002). Her film appearances include Volunteers (1985), Sleepless in Seattle (1993), Now and Then (1995), That Thing You Do! (1996), Jingle All the Way (1996), The Story of Us (1999), Runaway Bride (1999), It's Complicated (2009), and Larry Crowne (2011), and she appeared in the television series The Good Wife and Girls. Rita Wilson (born Margarita Ibrahimoff October 26, 1956) is an American actress, singer, and producer. |
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